Aquamarine

In the United States, aquamarines can be found at the summit of Mt. Antero in the Sawatch Range in central Colorado. In Brazil, there are mines in the states of Minas Gerais, Espírito Santo and Bahia. Zambia also produces nice aquamarine as well as Madagascar, Malawi, Tanzania and Kenya. Much of today's aquamarine is heated to give it a better color blue. The deeper the blue color, the more valuable the gem is considered. Three Beryl Crystals - Aquamarine rough crystal in the center.

The biggest aquamarine ever mined was found at the city of Marambaia, Minas Gerais, Brazil, in 1910. It weighed over 110 kg, and its dimensions were 48.5 cm long and 42 cm in diameter.

Aquamarine is the official state gem of Colorado.

Culture and historical/mythical usage
Aquamarine is the birthstone associated with March. It is also the gemstone for the 19th Anniversary.
People in the Middle Ages thought that aquamarine could magically overcome the effects of poison.
Ancient sailors traveled with aquamarine crystals, believing that it would ensure a safe passage, and often slept with the stones under their pillow to ensure sound sleep. They believed the siren’s (mermaid) fish-like lower body was made of aquamarine

Aquamarine
Aquamarine (Lat. aqua marina, "water of the sea") is a gemstone-quality transparent variety of beryl, having a delicate blue or  turquoise color, suggestive of the tint of seawater. It's closely related to the gem emerald. Colors vary and yellow beryl, called heliodor; rose pink beryl, morganite; and white beryl, goshenite are known.

Aquamarine is a beryl with a hexagonalcrystal structure and a chemical formula of Be 3Al 2Si 6O 18, a berylliumaluminiumsilicate mineral. It has a specific gravity of 2.68 to 2.74 and a Mohs hardness of from 7.5 to 8. Aquamarine typically is on the low end of the specific gravity range, normally at less than 2.7. The pink variety exhibits a high specific gravity of around 2.8. Refractive indices range around 1.57 to 1.58.

It occurs at most localities which yield ordinary beryl, some of the finest coming from Russia. The gem-gravel placer deposits of Sri Lanka contain aquamarine. Clear yellow beryl, such as occurs in Brazil, is sometimes called aquamarine chrysolite. When corundum presents the bluish tint of typical aquamarine, it is often termed Oriental aquamarine.

Chrysocolla

Chrysocolla (hydrated coppersilicate) is a mineral, CuSiO 3·nH 2O. It is of secondary origin and forms in the oxidation zones of copper ore bodies. Associated minerals are quartz, limonite, azurite, malachite, cuprite, and other secondary copper minerals.

Chrysocolla is an attractive blue-green colour and is minor ore of copper, having a hardness of 2.5 to 3.5. It is also used as an ornamental stone. It is typically found as glassy botryoidal or rounded masses and crusts, or vein fillings. Because of its light color, it is sometimes confused with turquoise. Commonly it occurs only as pourous crusts unsuitable for gem use, but high quality, gem grade Chrysocolla can be translucent and is highly prized.

The name comes from the Greek chrysos, "gold", and kolla, "glue", in allusion to the name of the material used to solder gold, and was first used by Theophrastus in 315 BCE.

Notable occurrences include Democratic Republic of Congo, Chile, Cornwall in England, and Arizona, Utah, New Mexico and Pennsylvania in the United States.

Spinel

The spinels are any of a class of minerals which crystallize in the isometric system with an octahedral habit. The general formula is as (X)(Y) 2O4, with X representing cations occupying tetrahedral sites and Y cations occupying octahedral sites. Divalent, trivalent, and quadrivalent cations can occupy the X and Y sites, and they include magnesium, zinc, iron, manganese, aluminium, chromium, titanium, and silicon.

The oxygen anions are arranged in a cubic close-packed structure. In the normal spinel structure, X cations occupy the tetrahedral sites, and Y the octahedral sites. For inverse spinels, half the Y cations occupy the tetrahedral sites, and both X and Y cations occupy the octahedral sites.

Important members of the spinel group include:
Spinel – MgAl 2O 4, after which this class of minerals is named
Gahnite - ZnAl 2O 4
Franklinite - (Fe,Mn,Zn)(Fe,Mn) 2O 4
Chromite - (Fe·Mg)Cr 2O 4
Magnetite - Fe 3O 4
Hercynite - FeAl 2O 4
Ulvospinel - TiFe 2O 4
Jacobsite - MnFe 2O 4
Trevorite - NiFe 2O 4
Ringwoodite - SiMg 2O 4, an abundant olivinepolymorph within the Earth's mantle from about 520 to 660 km depth, and a rare mineral in meteorites.

True spinel has long been found in the gemstone-bearing gravel of Sri Lanka and in limestones of Myanmar and Thailand.
Spinel usually occurs in isometric crystals, octahedrons, usually twinned. It has an imperfect octahedral cleavage and a conchoidal fracture. Its hardness is 8, its specific gravity is 3.5-4.1 and it is transparent to opaque with a vitreous to dull lustre. It may be colorless, but is usually various shades of red, blue, green, yellow, brown or black. There is a unique natural white spinel, now lost, that surfaced briefly in what is now Sri Lanka. Another famous spinel is the Black Prince's Ruby in the British Crown Jewels.

The transparent red spinels are called spinel-rubies or balas-rubies and were often confused with actual rubies in ancient times. "Balas" is derived from Balascia, the ancient name for Badakhshan, a region in central Asia situated in the upper valley of the Kokcha river, one of the principal tributaries of the Oxus river. Yellow spinel is called rubicelle and violet-colored manganese-bearing spinel is called almandine.

Spinel is found as a metamorphic mineral, and also as a primary mineral in basic rocks, because in such magmas the absence of alkalis prevents the formation of feldspars and any aluminium oxide present will form corundum or combine with magnesia to form spinel. This is why spinel and ruby are often found together.

Spinel, (Mg,Fe)(Al,Cr) 2O 4, is common in peridotite in the uppermost Earth's mantle, between the Mohorovicic discontinuity (the Moho) and a depth of 70 kilometers or so; below that depth, the spinel (if present) becomes increasingly rich in chromium, as with increasing depth, pyrope-rich garnet becomes the more stable aluminous mineral in peridotite. At depths significantly shallower than the Moho, calcic plagioclase is the more stable aluminous mineral in peridotite.

Mexican Black Spinel
Known to the Aztec and ancient Mayan civilizations, Indian legends indicate that this gemstone was worn in battle for personal protection to ward off evil spirits and attract wealth to the stone bearer. Lost for centuries, the source of Mexican Black Spinel has been re-discovered in Mexico's Nayarit Province.

 

Amethyst

Amethyst (SiO 2) is a violet or purple variety of quartz often used as an ornament. The name comes from the Greeka (not) and methuskein ("to intoxicate"), a reference to the belief that the stone protected its owner from drunkenness; the ancient Greeks and Romans wore amethyst and made drinking vessels of it in the belief that it would prevent intoxication.

Chemistry
In the 20th century, the color of amethyst was attributed to the presence of manganese. However, since it is capable of being greatly altered and even discharged by heat, the color was believed by some authorities to be from an organic source. Ferricthiocyanate was suggested, and sulfur was said to have been detected in the mineral. On exposure to heat, amethyst generally becomes yellow, and much of the citrine, cairngorm, or yellow quartz of jewelry is said to be merely "burnt amethyst." Veins of amethystine quartz are apt to lose their color on the exposed outcrop.

Composition
Amethyst is composed of an irregular superposition of alternate lamellae of right-handed and left-handed quartz. It has been shown that this structure may be due to mechanical stresses. As a consequence of this composite formation, amethyst is apt to break with a rippled fracture or to show "thumb markings," and the intersection of two sets of curved ripples may produce on the fractured surface a pattern something like that of "engine turning." Some mineralogists, following Sir David Brewster, apply the name of amethyst to all quartz which exhibits this structure, regardless of color. Because it has a hardness of 7 on the Mohs scale, amethyst is treasured for its use in jewelry. However, it is still just 1/15 as hard as diamond.
History- Amethyst was used as a gemstone by the ancient Egyptians and was largely employed in antiquity for intaglios. Beads of amethyst are found in Anglo-Saxon graves in England. It is a widely distributed mineral, but fine, clear specimens that are suitable for cutting as ornamental stones are confined to comparatively few localities. Such crystals occur either in the cavities of mineral-veins and in granitic rocks, or as a lining in agategeotes. A huge geode, or "amethyst-grotto," from near Santa Cruz in southern Brazil was exhibited at the Düsseldorf Exhibition of 1902. Many of the hollow agates of Brazil and Uruguay contain a crop of amethyst crystals in the interior. Much fine amethyst comes from Russia, especially from near Mursinka in the Ekaterinburg district, where it occurs in drusy cavities in granitic rocks. Many localities in India yield amethyst; and it is found also in Sri Lanka, chiefly as pebbles.

Alternate Terminology Due to its popularity as a gemstone, several descriptive terms have been coined in the gem trade to describe the varying colors of amethyst. "Rose de France" is usually a pale pinkish lavender or lilac shade (usually the least-sought color). The most prized color is an intense violet with red flashes and is called "Siberian," although gems of this color may occur from several locations other than Siberia, notably Uruguay and Zambia. In more recent times, certain gems (usually of Bolivian origin) that have shown alternate bands of amethyst purple with citrine orange have been given the name ametrine.
Purple corundum, or sapphire of amethystine tint, is called Oriental amethyst, but this expression is often applied by jewelers to fine examples of the ordinary amethystine quartz, even when not derived from eastern sources. Professional gemological associations, such as the Gemological Institute of America (GIA) or the American Gemological Society ( AGS), discourage the use of the term "Oriental amethyst" to describe any gem, as it may be misleading.
The Second Book of Pseudo-Albertus Maqnus, Of the Vertues of Certaine Stones, refers to amethysts by the name Amarictus.

Geographic distribution
Amethyst occurs at many localities in the United States, but these specimens are rarely fine enough for use in jewelry. Among these may be mentioned Amethyst Mountain, Texas; Yellowstone National Park; Delaware County, Pennsylvania; Haywood County, North Carolina; and Deer Hill and Stow, Maine. It is found also in the Lake Superior region. Amethyst is relatively common in northwestern Ontario, and in various locations throughout Nova Scotia, but uncommon elsewhere in Canada. Amethyst is produced in abudance from the state of Minas Gerais in Brazil where it occurs in large geodes within volcanic rocks.

Value
Traditionally included in the cardinal, or most valuable, gemstones (along with diamond, sapphire, ruby, and emerald), amethyst has lost much of its value due to the discovery of extensive deposits in locations such as Brazil.

 

Chrysoberyl

The mineral or gemstone chrysoberyl, not to be confused with beryl, is an aluminate of beryllium with the formula BeAl 2O4. Chrysoberyl is transparent to translucent and sometimes chatoyant. An interesting feature of uncut crystals of chyrsoberyl are the cyclic twins called trillings. These twinned crystals have a hexagonal appearance, but are the result of a triplet of twins with each "twin" taking up 120 degrees of the cyclic trilling. The word chrysoberyl is derived from the Greekchrysos, "golden," and beryllos, of uncertain etymology.

Occurrence
Chrysoberyl occurs in granitic rocks, pegmatites and micaschists; often it is found in alluvial deposits. It has also been found in contact metamorphic deposits of dolomiticmarble with corundum, and in fluorine bearing skarns. Most chrysoberyl is recovered from river sands and gravels.

Alexandrite variety
The alexandrite variety displays a color change (alexandrite effect) dependent upon light, along with strong pleochroism. Alexandrite results from small scale replacement of aluminium by chromium oxide, which is responsible for alexandrite's characteristic green to red color change. Alexandrite from the Ural Mountains in Russia is green by daylight and red by incandescent light. Other varieties of alexandrite may be yellowish or pink in daylight and a columbine or raspberry red by incandescent light. The optimum or "ideal" color change would be fine emerald green to fine purplish red, but this is exceedingly rare. Because of their rarity and the color change capability, "ideal" alexandrite gems are some of the most expensive in the world.

Alexandrite was first discovered in 1831 in an emerald mining region of the Ural Mountains in Russia. The name comes from Tsar Alexander II of Russia, on whose birthday the gem was discovered in that country. It was named "alexandrite" in his honor by the mineralogist Adolf Erik Nordenskiöld. It is an interesting coincidence that the Russian national colors are green and red, which may have originated from this gem.

The finest alexandrites were found in the Ural Mountains, the largest cut stones being in the 30 carat (6 g) range, though many fine examples have been discovered in Sri Lanka (up to 65 cts.), India (Andhra Pradesh), Brazil, Myanmar, and especially Zimbabwe (small stones usually under 1 carat (200 mg) but with intense color change). Overall, stones from any locale over 5 carats (1 g) would be considered extremely rare, especially gems with fine color change. Alexandrite is both hard and tough, making it very well suited to wear in jewelry.
The gem has given rise to the adjective "alexandritic", meaning any transparent gem or material which shows a noted change in color between natural and incandescent light. Some other gem varieties of which alexandritic specimens have been found include sapphire, garnet, and spinel.
Some gemstones described as lab-grown (synthetic) alexandrite are actually corundum laced with trace elements (e.g., vanadium) or color-change spinel and are not actually chrysoberyl. As a result, they would be more accurately described as simulated alexandrite rather than synthetic.Synthetic alexandrite is used as an active laser medium. Alexandrite laser crystals tend to be round, with a pale brown tint.